Temperature-triggered gate opening for gas adsorption in microporous manganese formate.

نویسندگان

  • Hyunuk Kim
  • Denis G Samsonenko
  • Minyoung Yoon
  • Ji Woong Yoon
  • Young Kyu Hwang
  • Jong-San Chang
  • Kimoon Kim
چکیده

Microporous manganese formate shows temperature-triggered gate opening for nitrogen and argon adsorption, which is not due to a structural change of the framework but due to dynamic opening of the pore aperture and/or sufficient kinetic energy of the adsorbates to overcome a diffusion barrier above a critical temperature.

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عنوان ژورنال:
  • Chemical communications

دوره 39  شماره 

صفحات  -

تاریخ انتشار 2008